Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides.
نویسندگان
چکیده
[Cp(2)Dy(thf)(μ-Cl)](2) (2) was synthesized from [Cp(2)Dy(μ-Cl)](n), which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased.
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عنوان ژورنال:
- Chemical communications
دوره 48 10 شماره
صفحات -
تاریخ انتشار 2012